620 research outputs found

    THE MARKET EFFECT OF EXPORTS

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    Slang. Problems of definition

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    The social and psychological complexities captured in slang vocabulary make the term difficult to define, leading some scholars to question whether the term is even usable for linguistics. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/3048

    The New Right - Fifth Amendment Right to Counsel

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    The New Right - Fifth Amendment Right to Counsel

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    Energy Security: Shaping the Consumer Decision Making Process in Emerging Economies

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    Energy security is a universal concern among all countries, with all nations struggling for a sustainable solution. Solar technologies are a particularly beneficial utility for emerging economies due to both geography and affordability. Solar Photovoltaics (PV) is one of the highest potential growth markets in emerging economies due to the ability for small-scale systems to be placed on residential rooftops. Distribution of PV to individual homeowners is a new buying and selling process for what has traditionally been a business-to-business marketplace. Because the consumer market is at an infant stage in emerging economies, the messages that PV companies send to consumers will ultimately shape consumer perception about renewable energy. Through content analysis of websites from 12 companies in two of the BRICS markets, this research explores the similarities and differences with regard to consumer-facing messages among companies of various sizes in the two markets

    Pedagogical Content Knowledge, Continuing Professional Development and Teachers’ Attitude Toward Science: A Structural Equation Model on Science Curriculum Implementation

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    The study's main objective was to determine the best-fit model for science curriculum implementation of public secondary science teachers in Region XII based on pedagogical content knowledge, continuing professional development, and teachers' attitudes toward science. This study used a stratified sampling technique to choose 400 respondents, a quantitative non-experimental causal research design, and mean, Pearson r, multiple regression, and structural equation model (SEM) as statistical tools. Survey questionnaires were deployed to the respondents using the online Google Form. Results revealed that the level of pedagogical content knowledge was very high, the level of continuing professional development was high, the level of attitude toward science was high, and the level of science curriculum implementation was very high. Moreover, pedagogical content knowledge, continuing professional development, and attitude toward science exhibited a significant relationship with science curriculum implementation. Furthermore, pedagogical content knowledge was the domain that best influences science curriculum implementation. Finally, among the five generated models, Model 5 best-fitted science curriculum implementation with pedagogical content knowledge in terms of subject matter knowledge, instructional objective and context, and knowledge of students' understanding, continuing professional development in terms of updating, reflective, and collaborative activities, and attitude toward science in terms of perceived dependency on context factors, self-efficacy, the difficulty of science teaching, and perceived relevance. Keywords: educational management, pedagogical content knowledge, continuing professional development, attitude toward science, science curriculum implementation, structural equation model, Philippines DOI: 10.7176/JEP/14-15-07 Publication date:May 31st 2023

    Peritektični čelici: značajke strukture, tehnologije legiranja i primjene

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    The article presents analysis of phase transformation characteristics, primary structure formation, alloying technology and usage of steels, which undergo a peritectic transformation during their solidification.U članku se predočuje analiza značajki fazne transformacije, nastanka primarne strukture, tehnologije legiranja i primjene čelika podvrgnutih peritektičkoj transformaciji pri skruΔ‡ivanju

    Anomalous pressure effect on the magnetic ordering in multiferroic BiMnO3

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    We report the magnetic field dependent dc magnetization and the pressure-dependent (pmax ~ 16 kbar) ac susceptibilities Xp(T) on both powder and bulk multiferroic BiMnO3 samples, synthesized in different batches under high pressure. A clear ferromagnetic (FM) transition is observed at TC ~ 100 K, and increases with magnetic field. The magnetic hysteresis behavior is similar to that of a soft ferromagnet. Ac susceptibility data indicate that both the FM peak and its temperature (TC) decrease simultaneously with increasing pressure. Interestingly, above a certain pressure (9 ~ 11 kbar), another peak appears at Tp ~ 93 K, which also decreases with increasing pressure, with both these peaks persisting over some intermediate pressure range (9 ~ 13 kbar). The FM peak disappears with further application of pressure; however, the second peak survives until present pressure limit (pmax ~ 16 kbar). These features are considered to originate from the complex interplay of the magnetic and orbital structure of BiMnO3 being affected by pressure.Comment: 4 pages,4 figures, publised in Physical Review B 78, 092404/200

    ΠœΠ΅Ρ‚ΠΈΠ»ΡŽΠ²Π°Π½Π½Ρ полоТСння 8 ΠΏΡ–Ρ€ΠΈΠ΄ΠΈΠ½ΠΎΠ²ΠΎΡ— частини ΠΌΠΎΠ»Π΅ΠΊΡƒΠ»ΠΈ N-(Π±Π΅Π½Π·ΠΈΠ»)-2-гідрокси-4-оксо-4Н-ΠΏΡ–Ρ€ΠΈΠ΄ΠΎ[1,2-a]ΠΏΡ–Ρ€ΠΈΠΌΡ–Π΄ΠΈΠ½-3-карбоксамідів як спроба посилСння Ρ—Ρ… Π°Π½Π°Π»Π³Π΅Ρ‚ΠΈΡ‡Π½ΠΈΡ… властивостСй

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    The chemical modification of the pyridine moiety of the molecule – displacement of the methyl group in position 8 ofΒ pyrido[1,2-a]pyrimidine nucleus has been considered as one of the possible versions to optimize the biological propertiesΒ of N-(benzyl)-2-hydroxy-4-oxo-4H-pyrido[1,2-a]pyrimidine-3-carboxamides. The synthesis of the research targetsΒ was carried out by the reaction of the corresponding benzylamines and ethyl 2-hydroxy-8-methyl-4-oxo-4H-pyrido[1,2-a]Β pyrimidine-3-carboxylate, in its turn obtained by condensation of 2-amino-4-methylpyridine (i.e. the product with theΒ methyl group in the intentionally required position) and triethyl methanetricarboxylate. The structure of the compoundsΒ obtained has been confirmed by the data of elemental analysis and NMR 1H spectroscopy, and in the case of opticallyΒ active 1-phenylethylamides additionally by polarimetry. The study of the analgesic properties of all N-(benzyl)-2-hydroxy-8-methyl-4-oxo-4H-pyrido[1,2-a]pyrimidine-3-carboxamides was performed on the standard experimental β€œacetic acidΒ writhing” model. At the same time, it has been found that our modification is accompanied with the increased biologicalΒ activity of exclusively para-substituted derivatives. For profound research 4-fluorobenzylamide exceeding Piroxicam andΒ Nabumetone by the level of the specific effect has been recommended as a potential new analgesic.Π’ качСствС ΠΎΠ΄Π½ΠΎΠ³ΠΎ ΠΈΠ· Π²ΠΎΠ·ΠΌΠΎΠΆΠ½Ρ‹Ρ… Π²Π°Ρ€ΠΈΠ°Π½Ρ‚ΠΎΠ² ΠΎΠΏΡ‚ΠΈΠΌΠΈΠ·Π°Ρ†ΠΈΠΈ биологичСских свойств N-(Π±Π΅Π½Π·ΠΈΠ»)-2-гидрокси-4-оксо-4Н-ΠΏΠΈΡ€ΠΈΠ΄ΠΎ[1,2-a]ΠΏΠΈΡ€ΠΈΠΌΠΈΠ΄ΠΈΠ½-3-карбоксамидов рассмотрСна химичСская модификация ΠΏΠΈΡ€ΠΈΠ΄ΠΈΠ½ΠΎΠ²ΠΎΠΉ части ΠΈΡ… ΠΌΠΎΠ»Π΅ΠΊΡƒΠ»Ρ‹ – ΠΏΠ΅Ρ€Π΅ΠΌΠ΅Ρ‰Π΅Π½ΠΈΠ΅ ΠΌΠ΅Ρ‚ΠΈΠ»ΡŒΠ½ΠΎΠΉ Π³Ρ€ΡƒΠΏΠΏΡ‹ Π² ΠΏΠΎΠ»ΠΎΠΆΠ΅Π½ΠΈΠ΅ 8 ΠΏΠΈΡ€ΠΈΠ΄ΠΎ[1,2-a]пиримидинового ядра. Π‘ΠΈΠ½Ρ‚Π΅Π· Ρ†Π΅Π»Π΅Π²Ρ‹Ρ… ΠΎΠ±ΡŠΠ΅ΠΊΡ‚ΠΎΠ² исслСдования осущСствлСн Ρ€Π΅Π°ΠΊΡ†ΠΈΠ΅ΠΉ ΡΠΎΠΎΡ‚Π²Π΅Ρ‚ΡΡ‚Π²ΡƒΡŽΡ‰ΠΈΡ… бСнзиламинов с этил-2-гидрокси-8-ΠΌΠ΅Ρ‚ΠΈΠ»-4-оксо-4Н-ΠΏΠΈΡ€ΠΈΠ΄ΠΎ[1,2-a]ΠΏΠΈΡ€ΠΈΠΌΠΈΠ΄ΠΈΠ½-3-карбоксилатом, Π² свою ΠΎΡ‡Π΅Ρ€Π΅Π΄ΡŒ, ΠΏΠΎΠ»ΡƒΡ‡Π΅Π½Π½Ρ‹ΠΌ кондСнсациСй 2-Π°ΠΌΠΈΠ½ΠΎ-4-ΠΌΠ΅Ρ‚ΠΈΠ»ΠΏΠΈΡ€ΠΈΠ΄ΠΈΠ½Π° (Ρ‚. Π΅. ΠΏΡ€ΠΎΠ΄ΡƒΠΊΡ‚Π° с ΠΌΠ΅Ρ‚ΠΈΠ»ΡŒΠ½ΠΎΠΉ Π³Ρ€ΡƒΠΏΠΏΠΎΠΉ Π² Π·Π°Π²Π΅Π΄ΠΎΠΌΠΎ Ρ‚Ρ€Π΅Π±ΡƒΠ΅ΠΌΠΎΠΌ ΠΏΠΎΠ»ΠΎΠΆΠ΅Π½ΠΈΠΈ) с триэтилмСтантрикарбоксилатом. Π‘Ρ‚Ρ€ΠΎΠ΅Π½ΠΈΠ΅ синтСзированных вСщСств ΠΏΠΎΠ΄Ρ‚Π²Π΅Ρ€ΠΆΠ΄Π΅Π½ΠΎ Π΄Π°Π½Π½Ρ‹ΠΌΠΈ элСмСнтного Π°Π½Π°Π»ΠΈΠ·Π° ΠΈ спСктроскопии 1Н ЯМР, Π° Π² случаС оптичСски Π°ΠΊΡ‚ΠΈΠ²Π½Ρ‹Ρ… 1-фСнилэтиламидов Π΄ΠΎΠΏΠΎΠ»Π½ΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎ Π΅Ρ‰Π΅ ΠΈ поляримСтричСски. Π˜Π·ΡƒΡ‡Π΅Π½ΠΈΠ΅ Π°Π½Π°Π»ΡŒΠ³Π΅Ρ‚ΠΈΡ‡Π΅ΡΠΊΠΈΡ… свойств всСх N-(Π±Π΅Π½Π·ΠΈΠ»)-2-гидрокси-8-ΠΌΠ΅Ρ‚ΠΈΠ»-4-оксо-4Н-ΠΏΠΈΡ€ΠΈΠ΄ΠΎ[1,2-a]ΠΏΠΈΡ€ΠΈΠΌΠΈΠ΄ΠΈΠ½-3-карбоксамидов ΠΏΡ€ΠΎΠ²Π΅Π΄Π΅Π½ΠΎ Π½Π° ΡΡ‚Π°Π½Π΄Π°Ρ€Ρ‚Π½ΠΎΠΉΒ ΡΠΊΡΠΏΠ΅Ρ€ΠΈΠΌΠ΅Π½Ρ‚Π°Π»ΡŒΠ½ΠΎΠΉ ΠΌΠΎΠ΄Π΅Π»ΠΈ уксуснокислых ΠΊΠΎΡ€Ρ‡Π΅ΠΉ. ΠŸΡ€ΠΈ этом Π½Π°ΠΉΠ΄Π΅Π½ΠΎ, Ρ‡Ρ‚ΠΎ прСдпринятая Π½Π°ΠΌΠΈ модификация сопровоТдаСтся усилСниСм биологичСской активности ΠΈΡΠΊΠ»ΡŽΡ‡ΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎ ΠΏΠ°Ρ€Π°Π·Π°ΠΌΠ΅Ρ‰Π΅Π½Π½Ρ‹Ρ… ΠΏΡ€ΠΎΠΈΠ·Π²ΠΎΠ΄Π½Ρ‹Ρ…. Для ΡƒΠ³Π»ΡƒΠ±Π»Π΅Π½Π½Ρ‹Ρ… испытаний Π² качСствС Π½ΠΎΠ²ΠΎΠ³ΠΎ ΠΏΠΎΡ‚Π΅Π½Ρ†ΠΈΠ°Π»ΡŒΠ½ΠΎΠ³ΠΎ Π°Π½Π°Π»ΡŒΠ³Π΅Ρ‚ΠΈΠΊΠ° Ρ€Π΅ΠΊΠΎΠΌΠ΅Π½Π΄ΠΎΠ²Π°Π½Β 4-Ρ„Ρ‚ΠΎΡ€Π±Π΅Π½Π·ΠΈΠ»Π°ΠΌΠΈΠ΄, прСвосходящий ΠΏΠΎ ΡƒΡ€ΠΎΠ²Π½ΡŽ спСцифичСского эффСкта ΠŸΠΈΡ€ΠΎΠΊΡΠΈΠΊΠ°ΠΌ ΠΈ НабумСтон.Π―ΠΊ ΠΎΠ΄ΠΈΠ½ Π· ΠΌΠΎΠΆΠ»ΠΈΠ²ΠΈΡ… Π²Π°Ρ€Ρ–Π°Π½Ρ‚Ρ–Π² ΠΎΠΏΡ‚ΠΈΠΌΡ–Π·Π°Ρ†Ρ–Ρ— Π±Ρ–ΠΎΠ»ΠΎΠ³Ρ–Ρ‡Π½ΠΈΡ… властивостСй N-(Π±Π΅Π½Π·ΠΈΠ»)-2-гідрокси-4-оксо-4Н-ΠΏΡ–Ρ€ΠΈΠ΄ΠΎ[1,2-a]ΠΏΡ–Ρ€ΠΈΠΌΡ–Π΄ΠΈΠ½-3-карбоксамідів розглянуто Ρ…Ρ–ΠΌΡ–Ρ‡Π½Ρƒ ΠΌΠΎΠ΄ΠΈΡ„Ρ–ΠΊΠ°Ρ†Ρ–ΡŽ ΠΏΡ–Ρ€ΠΈΠ΄ΠΈΠ½ΠΎΠ²ΠΎΡ— частини Ρ—Ρ… ΠΌΠΎΠ»Π΅ΠΊΡƒΠ»ΠΈ – пСрСміщСння ΠΌΠ΅Ρ‚ΠΈΠ»ΡŒΠ½ΠΎΡ— Π³Ρ€ΡƒΠΏΠΈ Ρƒ полоТСння 8 ΠΏΡ–Ρ€ΠΈΠ΄ΠΎ[1,2-a]ΠΏΡ–Ρ€ΠΈΠΌΡ–Π΄ΠΈΠ½ΠΎΠ²ΠΎΠ³ΠΎ ядра. Π‘ΠΈΠ½Ρ‚Π΅Π· Ρ†Ρ–Π»ΡŒΠΎΠ²ΠΈΡ…Β ΠΎΠ±β€™Ρ”ΠΊΡ‚Ρ–Π² дослідТСння здійснСно Ρ€Π΅Π°ΠΊΡ†Ρ–Ρ”ΡŽ Π²Ρ–Π΄ΠΏΠΎΠ²Ρ–Π΄Π½ΠΈΡ… Π±Π΅Π½Π·ΠΈΠ»Π°ΠΌΡ–Π½Ρ–Π² Π· Π΅Ρ‚ΠΈΠ»-2-гідрокси-8-ΠΌΠ΅Ρ‚ΠΈΠ»-4-оксо-4Н-ΠΏΡ–Ρ€ΠΈΠ΄ΠΎ[1,2-a]ΠΏΡ–Ρ€ΠΈΠΌΡ–Π΄ΠΈΠ½-3-карбоксилатом, Ρƒ свою Ρ‡Π΅Ρ€Π³Ρƒ, ΠΎΠ΄Π΅Ρ€ΠΆΠ°Π½ΠΈΠΌ ΠΊΠΎΠ½Π΄Π΅Π½ΡΠ°Ρ†Ρ–Ρ”ΡŽ 2-Π°ΠΌΡ–Π½ΠΎ-4-ΠΌΠ΅Ρ‚ΠΈΠ»ΠΏΡ–Ρ€ΠΈΠ΄ΠΈΠ½ΡƒΒ (Ρ‚ΠΎΠ±Ρ‚ΠΎ ΠΏΡ€ΠΎΠ΄ΡƒΠΊΡ‚Ρƒ Π· ΠΌΠ΅Ρ‚ΠΈΠ»ΡŒΠ½ΠΎΡŽ Π³Ρ€ΡƒΠΏΠΎΡŽ Π² Π·Π°Π²Ρ–Π΄ΠΎΠΌΠΎ Π½Π΅ΠΎΠ±Ρ…Ρ–Π΄Π½ΠΎΠΌΡƒ ΠΏΠΎΠ»ΠΎΠΆΠ΅Π½Π½Ρ–) Π· триСтилмСтантрикарбоксилатом. Π‘ΡƒΠ΄ΠΎΠ²Ρƒ синтСзованих Ρ€Π΅Ρ‡ΠΎΠ²ΠΈΠ½ ΠΏΡ–Π΄Ρ‚Π²Π΅Ρ€Π΄ΠΆΠ΅Π½ΠΎ Π΄Π°Π½ΠΈΠΌΠΈ Π΅Π»Π΅ΠΌΠ΅Π½Ρ‚Π½ΠΎΠ³ΠΎ Π°Π½Π°Π»Ρ–Π·Ρƒ Ρ‚Π° спСктроскопії 1Н ЯМР,Β Π° Ρƒ Π²ΠΈΠΏΠ°Π΄ΠΊΡƒ ΠΎΠΏΡ‚ΠΈΡ‡Π½ΠΎ Π°ΠΊΡ‚ΠΈΠ²Π½ΠΈΡ… 1-Ρ„Π΅Π½Ρ–Π»Π΅Ρ‚ΠΈΠ»Π°ΠΌΡ–Π΄Ρ–Π² Π΄ΠΎΠ΄Π°Ρ‚ΠΊΠΎΠ²ΠΎ Ρ‰Π΅ ΠΉ поляримСтрично. ВивчСння Π°Π½Π°Π»Π³Π΅Ρ‚ΠΈΡ‡Π½ΠΈΡ… властивостСй усіх N-(Π±Π΅Π½Π·ΠΈΠ»)-2-гідрокси-8-ΠΌΠ΅Ρ‚ΠΈΠ»-4-оксо-4Н-ΠΏΡ–Ρ€ΠΈΠ΄ΠΎ[1,2-a]ΠΏΡ–Ρ€ΠΈΠΌΡ–Π΄ΠΈΠ½-3-карбоксамідів ΠΏΡ€ΠΎΠ²Π΅Π΄Π΅Π½ΠΎ Π½Π° стандартній Π΅ΠΊΡΠΏΠ΅Ρ€ΠΈΠΌΠ΅Π½Ρ‚Π°Π»ΡŒΠ½Ρ–ΠΉ ΠΌΠΎΠ΄Π΅Π»Ρ– оцтовокислих ΠΊΠΎΡ€Ρ‡Ρ–Π². ΠŸΡ€ΠΈ Ρ†ΡŒΠΎΠΌΡƒ Π·Π½Π°ΠΉΠ΄Π΅Π½ΠΎ,Β Ρ‰ΠΎ здійснСна Π½Π°ΠΌΠΈ модифікація ΡΡƒΠΏΡ€ΠΎΠ²ΠΎΠ΄ΠΆΡƒΡ”Ρ‚ΡŒΡΡ посилСнням Π±Ρ–ΠΎΠ»ΠΎΠ³Ρ–Ρ‡Π½ΠΎΡ— активності Π²ΠΈΠΊΠ»ΡŽΡ‡Π½ΠΎ ΠΏΠ°Ρ€Π°Π·Π°ΠΌΡ–Ρ‰Π΅Π½ΠΈΡ… ΠΏΠΎΡ…Ρ–Π΄Π½ΠΈΡ…. Для ΠΏΠΎΠ³Π»ΠΈΠ±Π»Π΅Π½ΠΈΡ… Π²ΠΈΠΏΡ€ΠΎΠ±ΠΎΠ²ΡƒΠ²Π°Π½ΡŒ як Π½ΠΎΠ²ΠΈΠΉ ΠΏΠΎΡ‚Π΅Π½Ρ†Ρ–ΠΉΠ½ΠΈΠΉ Π°Π½Π°Π»Π³Π΅Ρ‚ΠΈΠΊ Ρ€Π΅ΠΊΠΎΠΌΠ΅Π½
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